TY - MGZN T1 - Nanostructures, optical properties, and imaging application of lead-sulfide nanocomposite coatings T3 - International journal of applied ceramic technology. - 1. 2004, 2, S. 119-128 A1 - Lu,Song Wei A1 - Schmidt,Helmut K. Y1 - 2011/02/18 N2 - Lead-sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre-photo-polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for prephoto-polymerization and increasing concentration. The absorption onset has a large blue shift from 0,41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre-photo-polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings. KW - Nanostruktur KW - Blei KW - Sulfide KW - Nanokristall KW - Nanokomposit KW - Absorption CY - Saarbrücken PB - Universitäts- und Landesbibliothek AD - Postfach 151141, 66041 Saarbrücken UR - http://scidok.sulb.uni-saarland.de/volltexte/2011/3073 ER -