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doi:10.22028/D291-47961 | Title: | Accessing zinc(i) via reductive elimination of cyclopentadienes |
| Author(s): | Pitz, Benjamin Danés, Sergi Morgenstern, Bernd Schäfer, André |
| Language: | English |
| Title: | Chemical Communications |
| Volume: | 62 |
| Issue: | 7 |
| Pages: | 2204-2207 |
| Publisher/Platform: | RSC |
| Year of Publication: | 2026 |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | The reaction between zincocenes and b-diketiminate zinc hydrides was investigated, and the compounds were found to undergo reductive elimination reactions, giving the corresponding zinc(I) species and cyclopentadienes as the elimination product. The zinc(I) compounds underwent disproportionation reactions in several cases and a ligand exchange reaction in one instance, which gave rise to octaisopropyldizincocene. |
| DOI of the first publication: | 10.1039/D5CC06448A |
| URL of the first publication: | https://doi.org/10.1039/D5CC06448A |
| Link to this record: | urn:nbn:de:bsz:291--ds-479619 hdl:20.500.11880/41948 http://dx.doi.org/10.22028/D291-47961 |
| ISSN: | 1364-548X 1359-7345 |
| Date of registration: | 1-Jun-2026 |
| Description of the related object: | Supplementary information |
| Related object: | https://www.rsc.org/suppdata/d5/cc/d5cc06448a/d5cc06448a1.xyz https://www.rsc.org/suppdata/d5/cc/d5cc06448a/d5cc06448a2.pdf https://www.rsc.org/suppdata/d5/cc/d5cc06448a/d5cc06448a3.cif |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Guido Kickelbick |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| d5cc06448a.pdf | 2,25 MB | Adobe PDF | View/Open |
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