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doi:10.22028/D291-22311 | Title: | Besonderheiten bei der Ozonolyse substituierter Cyclopentene |
| Other Titles: | Details on Ozonolyses of Substituted Cyclopentenes |
| Author(s): | Schank, Kurt Susanne Pistorius Matthias Weiter Frank Werner |
| Other involved persons: | Heisel, Thomas |
| Other involved corporations: | Schank, Kurt |
| Language: | German |
| Year of Publication: | 1995 |
| OPUS Source: | J. Prakt. Chem. 1995 |
| SWD key words: | Ozonolyse |
| Free key words: | oxygenierende Ringerweiterung substituierte Cyclopentene oxygenating ring expansion ozonolysis subsituted Cyclopentenes |
| DDC notations: | 000 Generalities |
| Publikation type: | Report |
| Abstract: | Die Bildung und Stabilität monomerer Ozonide von Cyclopentenen werden in Abhängigkeit von der Substitution studiert. Bisherige Annahmen müssen revidiert werden, eine mechanistische Alternative über oxygenierende Ringerweiterung (Monosauerstoff-Transfer) und anschließende peroxidische Verbrückung (Disauerstoff-Transfer) wird diskutiert. Formation and stability of monomeric ozonides of cyclopentenes are studied depending upon substitution. Assumptions hitherto made must be revised. A mechanistic alternative including a sequence of oxygenative ring-enlargement (Transfer of one oxygen) and final formation of a peroxide bridge (Transfer of two oxygens) is discussed. |
| Link to this record: | urn:nbn:de:bsz:291-scidok-248 hdl:20.500.11880/22367 http://dx.doi.org/10.22028/D291-22311 |
| Date of registration: | 29-Aug-2000 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Ozonolyse_sub_Cyclopentene.pdf | 35,77 kB | Adobe PDF | View/Open |
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