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doi:10.22028/D291-22562 | Title: | On the differing Lewis basicity of In(I) compared with Sn(II) in molecular indium-tin and thallium-tin alkoxides [Chemistry of alkoxystannates ; 6] |
| Author(s): | Veith, Michael Kunze, Klaus |
| Language: | English |
| Year of Publication: | 1991 |
| OPUS Source: | Angewandte Chemie / International edition in English. - 30. 1991, 1, S. 95-97 |
| SWD key words: | Indium-Indium-Bindung Thallium Alkoholate |
| DDC notations: | 540 Chemistry |
| Publikation type: | Journal Article |
| Abstract: | A nearly linear arrangement of the four metal atoms Cr, Sn, In, and Mo, as well as an eclipsed arrangement of the [M(CO)5] fragments, in complex 1 was shown by X-ray structure analysis. Complex 1 was formed by successive addition of [M(CO)5 (thf)] to the bridgehead centers of Sn(OtBu)3In. The two centers differ in their basicity. |
| Link to this record: | urn:nbn:de:bsz:291-scidok-18252 hdl:20.500.11880/22618 http://dx.doi.org/10.22028/D291-22562 |
| Date of registration: | 19-Feb-2009 |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie SE - INM Leibniz-Institut für Neue Materialien |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes INM |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| ve199108_1.pdf | 354,78 kB | Adobe PDF | View/Open |
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