Please use this identifier to cite or link to this item:
doi:10.22028/D291-23848
Title: | Novel insertions of carbene homologs into Metal-Eta-5-Cp bonds : sandwich complexes with Ge2Ni and Sn2Ni cores |
Author(s): | Veith, Michael Stahl, Lothar |
Language: | English |
Year of Publication: | 1993 |
OPUS Source: | Angewandte Chemie / International edition in English. - 32. 1993, 1, S. 106-107 |
SWD key words: | Carben-Carben-Umlagerung |
DDC notations: | 540 Chemistry |
Publikation type: | Journal Article |
Abstract: | An unsymmetrical bridging Cp(~)ligand is the striking structural element in 1. Compound 1 can be considered as an intermediate of the reaction in which GeMe2Si(NtBu)2 attacks [Cp2Ni] as a Lewis acid, and inserts into the Ni-Cp bond. The analogous Sn complex has a symmetric structure.(~) |
Link to this record: | urn:nbn:de:bsz:291-scidok-18100 hdl:20.500.11880/23904 http://dx.doi.org/10.22028/D291-23848 |
Date of registration: | 4-Dec-2008 |
Faculty: | SE - Sonstige Einrichtungen |
Department: | SE - INM Leibniz-Institut für Neue Materialien NT - Chemie |
Collections: | INM SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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