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doi:10.22028/D291-37840 | Title: | Modulation of the nuclearity of molecular Mg(ii)-phosphates : solid-state structural change involving coordinating solvents |
| Author(s): | Santra, Biswajit Narayanan, Ramakirushnan Suriya Kalita, Pankaj Kumar, Vierandra Mandal, Debdeep Gupta, Vivek Zimmer, Michael Huch, Volker Chandrasekhar, Vadapalli Scheschkewitz, David Schulzke, Carola Jana, Anukul |
| Language: | English |
| Title: | Dalton Transactions |
| Volume: | 48 |
| Issue: | 24 |
| Pages: | 8853-8860 |
| Publisher/Platform: | Royal Society of Chemistry |
| Year of Publication: | 2019 |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Herein, we report the synthesis and molecular structures of various magnesium(II)-phosphate monoesters. By using a bulky aryl substituted phosphate monoester, ArOPO3H2 (Ar = 2,6-(CHPh2)2-4-tBu-C6H2), we have reproducibly assembled mono-, di-, tetra- (cage and ring), hexa-, and polynuclear magnesium(II)-phosphate monoesters. Interestingly, the hexanuclear magnesium(II)-phosphate monoester encapsulates an open-cage dodecanuclear water cluster. |
| DOI of the first publication: | 10.1039/c9dt00687g |
| URL of the first publication: | https://pubs.rsc.org/en/content/articlelanding/2019/dt/c9dt00687g |
| Link to this record: | urn:nbn:de:bsz:291--ds-378406 hdl:20.500.11880/34219 http://dx.doi.org/10.22028/D291-37840 |
| Date of registration: | 7-Nov-2022 |
| Description of the related object: | Supplementary files |
| Related object: | https://www.rsc.org/suppdata/c9/dt/c9dt00687g/c9dt00687g1.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. David Scheschkewitz |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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