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doi:10.22028/D291-37845 | Title: | The Addition of a Cyclopropyl Alkyne to an Asymmetrically-Substituted Disilene: A Mechanistic Study |
| Author(s): | Henry, Andrew T. Bourque, Jeremy L. Vacirca, Isabell Scheschkewitz, David Baines, Kim M. |
| Language: | English |
| Title: | Organometallics |
| Volume: | 38 |
| Issue: | 7 |
| Pages: | 1622–1626 |
| Publisher/Platform: | American Chemical Society |
| Year of Publication: | 2019 |
| Free key words: | Group 14 compounds Hydrocarbons Phenyls Silicon Substituents |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | The addition of (2-ethynyl-3-methoxy-2-methylcyclopropyl)benzene to Tip2Si═SiTipPh, a disilene with an asymmetric substitution pattern, was investigated. The regiochemistry of the ring-opened products indicates a stepwise mechanism with a biradical intermediate. The results are consistent with those obtained in similar experiments with symmetrically substituted disilenes. |
| DOI of the first publication: | 10.1021/acs.organomet.9b00054 |
| URL of the first publication: | https://pubs.acs.org/doi/10.1021/acs.organomet.9b00054 |
| Link to this record: | urn:nbn:de:bsz:291--ds-378458 hdl:20.500.11880/34221 http://dx.doi.org/10.22028/D291-37845 |
| ISSN: | 1520-6041 0276-7333 |
| Date of registration: | 7-Nov-2022 |
| Description of the related object: | Supporting Information |
| Related object: | https://pubs.acs.org/doi/suppl/10.1021/acs.organomet.9b00054/suppl_file/om9b00054_si_001.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. David Scheschkewitz |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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