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doi:10.22028/D291-43956 | Title: | A Lead(II) Substituted Triplet Carbene |
| Author(s): | Dankert, Fabian Messelberger, Julian Authesserre, Ugo Swain, Abinash Scheschkewitz, David Morgenstern, Bernd Munz, Dominik |
| Language: | English |
| Title: | Journal of the American Chemical Society |
| Volume: | 146 |
| Issue: | 43 |
| Pages: | 29630-29636 |
| Publisher/Platform: | ACS |
| Year of Publication: | 2024 |
| Free key words: | Aromatic Compounds Carbene Compounds Hydrocarbons Irradiation Particulate Matter |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Reaction of the pincer-type ligand L3 supported complex [L3PbBr]- [BArF24] (1) with Li[(C(�N2)TMS)] furnishes [L3Pb(C(�N2)TMS)][BArF24] (2). Diazo-compound 2 eliminates dinitrogen upon irradiation affording formal plumba-alkyne 3, which persists in cold fluoroarene solutions. Variable temperature UV/Vis and NMR spectroscopies in combination with quantum-chemical calculations identify 3 as a metal-substituted triplet carbene. In-crystallo irradiation of [L3Pb(C(� N2)TMS)(tol)][BArF24] (2·tol) provides a snapshot of intermolecular C−H bond insertion with toluene (4). |
| DOI of the first publication: | 10.1021/jacs.4c10205 |
| URL of the first publication: | https://pubs.acs.org/doi/10.1021/jacs.4c10205 |
| Link to this record: | urn:nbn:de:bsz:291--ds-439562 hdl:20.500.11880/39344 http://dx.doi.org/10.22028/D291-43956 |
| ISSN: | 1520-5126 0002-7863 |
| Date of registration: | 10-Jan-2025 |
| Description of the related object: | Supporting Information |
| Related object: | https://pubs.acs.org/doi/suppl/10.1021/jacs.4c10205/suppl_file/ja4c10205_si_001.pdf https://pubs.acs.org/doi/suppl/10.1021/jacs.4c10205/suppl_file/ja4c10205_si_002.xyz |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Guido Kickelbick NT - Prof. Dr. Dominik Munz NT - Prof. Dr. David Scheschkewitz |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| dankert-et-al-2024-a-lead(ii)-substituted-triplet-carbene.pdf | 3,13 MB | Adobe PDF | View/Open |
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