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doi:10.22028/D291-46582 | Title: | Stereoselective Syntheses of Cyclic Microsclerodermin Derivatives |
| Author(s): | Bauer, Kevin Kazmaier, Uli |
| Language: | English |
| Title: | Chemistry |
| Volume: | 31 |
| Issue: | 60 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2025 |
| Free key words: | Arndt-Eistert homologation cyclic peptides microsclerodermins sakurai reaction tetrahydrofurans |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Starting from l-xylose and d-arabinose, six different cyclic microscleroderma derivatives were successfully obtained. Key steps of the syntheses are, on the one hand, Sakurai allylations, whose stereochemical course depends on the Lewis acid used, and on the other hand, photochemical Wolff rearrangements in the presence of complex aminofuranosides. Finally, aromatic side chains were introduced via cross metathesis. |
| DOI of the first publication: | 10.1002/chem.202502459 |
| URL of the first publication: | https://doi.org/10.1002/chem.202502459 |
| Link to this record: | urn:nbn:de:bsz:291--ds-465824 hdl:20.500.11880/40828 http://dx.doi.org/10.22028/D291-46582 |
| ISSN: | 1521-3765 0947-6539 |
| Date of registration: | 26-Nov-2025 |
| Description of the related object: | Supporting Information |
| Related object: | https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202502459&file=chem70250-sup-0001-SuppMat.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Chemistry A European J - 2025 - Bauer - Stereoselective Syntheses of Cyclic Microsclerodermin Derivatives.pdf | 1,62 MB | Adobe PDF | View/Open |
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