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-no DOI; please use other URI| Title: | Stereoselective Synthesis of Complex α‐Amino Acid Derivatives Using Boron and Palladium Chemistry |
| Author(s): | Priester, Ronja Kazmaier, Uli |
| Language: | English |
| Title: | Zeitschrift für Anorganische und Allgemeine Chemie |
| Volume: | 651 |
| Issue: | 17 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2025 |
| Free key words: | allylic alkylation amino acids boron Matteson homologation palladium |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Matteson homologation of boronic acid esters allows the highly stereoselective synthesis of complex allyl alcohols, which are valuable substrates for palladium-catalyzed allylic alkylations. With highly reactive amino acid zinc enolates, trans-configured γ, δ-unsaturated amino acid derivatives are obtained as single regioisomer. Excellent 1,4-chirality transfer from the allylic substrate into the stereogenic α-center of the amino acid is observed in all cases. |
| DOI of the first publication: | 10.1002/zaac.202500160 |
| URL of the first publication: | https://doi.org/10.1002/zaac.202500160 |
| Link to this record: | urn:nbn:de:bsz:291--ds-468945 hdl:20.500.11880/41080 |
| ISSN: | 1521-3749 0044-2313 |
| Date of registration: | 6-Feb-2026 |
| Description of the related object: | Supporting Information |
| Related object: | https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fzaac.202500160&file=zaac70035-sup-0001-SuppData-S1.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Size | Format | |
|---|---|---|---|
| Zeitschrift anorg allge chemie - 2025 - Priester - Stereoselective Synthesis of Complex ‐Amino Acid Derivatives Using.pdf | 843,26 kB | Adobe PDF | View/Open |
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