Please use this identifier to cite or link to this item:
doi:10.22028/D291-46030 | Title: | Synthesis of oxylipids via a boronic ester cycloetherification approach |
| Author(s): | Tost, Markus Kazmaier, Uli |
| Language: | English |
| Title: | Organic Chemistry Frontiers |
| Volume: | 12 |
| Issue: | 10 |
| Pages: | 3288-3292 |
| Publisher/Platform: | RSC |
| Year of Publication: | 2025 |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Deprotonated trimethylsilylethanol can be used as a nucleophile in Matteson homologations. This O-protection group is stable under the usual reaction conditions of the Matteson reaction, but after two further homologation steps it is automatically cleaved off and cycloetherification can take place, giving rise to substituted tetrahydrofurans in a highly stereoselective fashion. This elegant protocol was used in the synthesis of various oxylipids. |
| DOI of the first publication: | 10.1039/D5QO00213C |
| URL of the first publication: | https://doi.org/10.1039/D5QO00213C |
| Link to this record: | urn:nbn:de:bsz:291--ds-460301 hdl:20.500.11880/40396 http://dx.doi.org/10.22028/D291-46030 |
| ISSN: | 2052-4129 |
| Date of registration: | 18-Aug-2025 |
| Description of the related object: | supplementary information |
| Related object: | https://www.rsc.org/suppdata/d5/qo/d5qo00213c/d5qo00213c1.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| d5qo00213c.pdf | 524,56 kB | Adobe PDF | View/Open |
This item is licensed under a Creative Commons License
